Calcite

Natural inorganic pigment

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Composition and Properties of Calcite

Calcite is the mineral form of calcium carbonate CaCO3. There are other forms of calcium carbonate such as marble and also aragonite and vaterite, all of which have been used in painting. Calcite can be found in nature mainly in the form of chalk which had been formed from the fossil remains of marine algae.

The pigment is very stable under normal conditions but it dissolves in all acids under the evolution of carbon dioxide gas. It is lightfast and it does not darken in contact with environmental pollutants such as hydrogen sulfide and is also compatible with all other pigments.

calcite-crystals

Pigment

calcite-Chalk-Champagne

Painted swatch

Names 

Alternative names

Chalk, lime white, St John’s white

Color Index

PW 18, CI 77220

Word origin

Chalk: from Old English cealc “chalk, soft white limestone; lime, plaster; pebble,” a West Germanic borrowing from Latin calx “limestone, lime (crushed limestone), small stone,” from Greek khalix “small pebble”
From Online Etymology Dictionary

Calcite: from German Calcit, coined by Austrian mineralogist Wilhelm Karl von Hardinger (1795-1871) from Latin calx (genitive calcis) “lime”.
From Online Etymology Dictionary

Spain Flag

Kreide, Kalzit

German

Spain Flag

Craie

French

Spain Flag

Creta

Italian

Spain Flag

Creta

Spanish

Preparation 

Chalk is being quarried in England, Belgium, Germany, and other European countries. The raw material is sometimes left to weather and is then ground under water and dried.

History of Use 

Chalk and the other forms of calcium carbonate have been in use since antiquity mainly as a component for grounds.

References

(1) Rohleder J. The history of chalk. In: Tegethoff F.W. (eds) Calcium Carbonate. Birkhäuser, Basel 2001

Examples of use

Dirk Bouts, The Entombment, probably 1450

Dieric_Bouts_Entombment

 

The upper part of the head covering of Mary is painted in chalk highlighted with small amounts of lead white. 

Identification

Fiber optics reflectance spectra (FORS)
IR Spectrum
Raman Spectrum

Raman-spectra-calciteSpectrum by Ian M. Bell, Robin J.H. Clark and Peter J. Gibbs, Raman Spectroscopic Library
University College of London

X-Ray Fluorescence Spektrum (XRF)

XRF Spectrum in the Free XRF Spectroscopy Database of Pigments Checker, CHSOS website.

calcite-Chalk-microphotograph

Microphotograph

image © Volker Emrath

Further Reading

References

(1) Gettens, R. J., West Fitzhugh, E. and Feller, R. L., Calcium Carbonate Whites in Artists’ Pigments. A Handbook of Their History and Characteristics, Vol. 2: A. Roy (Ed.) Oxford University Press 1993, p. 203-26. Available as pdf from the National Gallery of Art.

(2) S. Muntwyler, J. Lipscher, HP. Schneider, Das Farbenbuch, 2nd. Ed., 2023, alataverlag Elsau, pp. 60-61.